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Filter Paper Grade 44 (3 µm)

Grade-44
Equivalent to Whatman Grade 44
Particle Retention: 3μm
Product Appearance: Good
Filtration Speed: Slow
Ash Content(%): < 0.01
Thickness(μm): 176
Basis Weight(g/m2): 77
Wet Burst(psi): 0.4

Availability: In Stock

Description

Ultra-fine quantitative filtration for the most demanding gravimetric accuracy requirements

In quantitative chemical analysis, the most significant source of error is often not the analytical instrument, but the loss or incomplete retention of fine precipitates during filtration. When precipitates are extremely fine or colloidal in nature, even minimal breakthrough can lead to measurable deviations in final gravimetric results.

Filter Paper Grade 44 is engineered for these high-precision conditions, where maximum particle retention is required and filtration speed becomes a secondary consideration. It is specifically optimized for fine precipitates such as barium sulfate (BaSO₄), cuprous oxide (Cu₂O), and metastannic acid systems.

What Filter Paper Grade 44 actually is

Filter Paper Grade 44 is an ashless quantitative cellulose filter paper manufactured from high-purity cotton linters under tightly controlled production conditions to ensure consistent pore structure, low extractables, and stable filtration behavior.

From a laboratory classification perspective, it belongs to: ultra-fine retention quantitative filtration media designed for high-precision gravimetric workflows.

It is intended for applications where:

  • Ultra-fine particle retention (~3 µm nominal) is required
  • Gravimetric accuracy depends on near-complete precipitation capture
  • Low ash content is essential to avoid post-ignition mass bias
  • Analytical reliability is prioritized over filtration throughput

Position in the filtration grade system

Grade 44 is positioned within the quantitative cellulose filter paper series as a high-retention grade designed for fine precipitation systems.

GradeApprox. RetentionFiltration Character
Grade 41~20 µmFast flow, coarse retention
Grade 43~16 µmBalanced flow and retention
Grade 40~8 µmMedium retention, stable gravimetric use
Grade 42~2.5 µmHighest retention, slowest flow
Grade 44~3 µmOptimized ultra-fine retention for specific precipitates

Grade 44 is not simply defined by pore size alone, but by its optimized retention behavior for specific inorganic precipitation systems where predictable filtration performance is critical.

Real laboratory behavior (why Grade 44 is selected)

1. Ultra-fine precipitation retention stability

Certain inorganic precipitates form extremely fine particles that may partially pass through medium-retention filter papers. Grade 44 minimizes this risk by providing enhanced retention stability in such systems.

2. Gravimetric mass accuracy protection

In gravimetric analysis, even small particle losses can introduce negative bias in final mass determination. Grade 44 helps maintain analytical integrity by ensuring near-complete capture of target precipitates.

3. Controlled slow filtration mechanism

Reduced filtration speed is a functional characteristic of high-retention media. This controlled flow ensures improved particle capture efficiency and more stable filtration front behavior.

Why laboratories choose Grade 44

Grade 44 is typically selected when analytical accuracy requirements exceed routine filtration conditions.

  • High-precision gravimetric determination of fine inorganic precipitates
  • Separation of difficult-to-retain compounds such as BaSO₄ and Cu₂O
  • Trace-level environmental and material purity analysis
  • Final-stage sample clarification before instrumental analysis

In these scenarios, Grade 44 functions as a precision control filter medium rather than a general-purpose laboratory consumable.

Technical Specifications

ParameterSpecification
Filter TypeAshless quantitative cellulose filter paper
Nominal Particle Retention~3 µm
Filtration SpeedSlow
Ash Content≤ 0.01%
MaterialHigh-purity cotton linters cellulose
Thickness~176 µm
Basis Weight~77 g/m²
Functional RoleUltra-high retention quantitative filtration medium

Typical applications

  • Gravimetric determination of ultra-fine inorganic precipitates (BaSO₄, Cu₂O, metastannic acid)
  • High-purity chemical and material analysis
  • Trace environmental suspended solids determination
  • Advanced laboratory quality control testing
  • High-precision soil and sediment fraction analysis
  • Final-stage pre-filtration for ICP / ICP-MS / AAS systems

Selection logic (how laboratories actually decide)

Observed RequirementRecommended Grade
Particle breakthrough in fine precipitatesGrade 44
Balanced speed and accuracyGrade 40 / 43
Fast routine filtrationGrade 41
Maximum fine-particle retention (slowest flow)Grade 42

Grade 44 is preferred when precipitate retention stability is more critical than throughput efficiency.

Analytical performance considerations

Grade 44 is widely used in workflows where:

  • Complete retention of target precipitates is required
  • Gravimetric mass accuracy must be maximized
  • Low ash residue is critical for high-purity analysis
  • Instrument contamination risk must be minimized

It is considered a high-precision analytical barrier medium within quantitative filtration systems.

Equivalent grade reference

ManufacturerEquivalent Grade
HawachGrade 44
WhatmanGrade 44
Advantec6 / 4A
Munktell391
Ahlstrom95
Macherey-Nagel640de

Ordering information

Cat#DescriptionEquivalent to WhatmanPackage(pcs/pk)
22011225Grade 44, Slow, 3um, 70mm1444-070100pcs/pk
22011226Grade 44, Slow, 3um, 90mm1444-090100pcs/pk
22011227Grade 44, Slow, 3um, 110mm1444-110100pcs/pk
22011228Grade 44, Slow, 3um, 125mm1444-125100pcs/pk
22011229Grade 44, Slow, 3um, 150mm1444-150100pcs/pk
22011230Grade 44, Slow, 3um, 180mm–100pcs/pk

Download PDF Datasheet

FAQ

Why is Grade 44 used for ultra-fine precipitate analysis?

Because it provides stable high-retention performance for fine inorganic precipitates where gravimetric accuracy is critical.

How does Grade 44 differ from Grade 42?

Grade 44 is optimized for specific fine precipitate systems with slightly higher nominal pore size, while Grade 42 provides maximum retention for broader ultra-fine filtration conditions.

Can Grade 44 be used for ICP or AAS sample preparation?

Yes. It is commonly used as a final-stage pre-filtration medium to remove fine particulates before instrumental analysis.

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